Wamser, Carl C. Department of Chemistry, Portland State University, Portland, Oregon.
- Carbocation rearrangements
- Migratory aptitude
- Other rearrangements to electron-deficient carbon
- Rearrangements to electron-deficient nitrogen or oxygen
- Free-radical rearrangements
- Sigmatropic rearrangements
- Additional Readings
A reaction in which an atom or bond moves or migrates, having been initially located at one site in a reactant molecule and ultimately located at a different site in a product molecule. A rearrangement reaction may involve several steps, but the key feature defining it as a rearrangement is that a bond shifts from one site of attachment to another. The simplest examples of rearrangement reactions are intramolecular, that is, reactions in which the product is simply a structural isomer of the reactant [reaction (1)].
The content above is only an excerpt.
for your institution. Subscribe
To learn more about subscribing to AccessScience, or to request a no-risk trial of this award-winning scientific reference for your institution, fill in your information and a member of our Sales Team will contact you as soon as possible.
to your librarian. Recommend
Let your librarian know about the award-winning gateway to the most trustworthy and accurate scientific information.
AccessScience provides the most accurate and trustworthy scientific information available.
Recognized as an award-winning gateway to scientific knowledge, AccessScience is an amazing online resource that contains high-quality reference material written specifically for students. Its dedicated editorial team is led by Sagan Award winner John Rennie. Contributors include more than 9000 highly qualified scientists and 39 Nobel Prize winners.
MORE THAN 8500 articles and Research Reviews covering all major scientific disciplines and encompassing the McGraw-Hill Encyclopedia of Science & Technology and McGraw-Hill Yearbook of Science & Technology
115,000-PLUS definitions from the McGraw-Hill Dictionary of Scientific and Technical Terms
3000 biographies of notable scientific figures
MORE THAN 17,000 downloadable images and animations illustrating key topics
ENGAGING VIDEOS highlighting the life and work of award-winning scientists
SUGGESTIONS FOR FURTHER STUDY and additional readings to guide students to deeper understanding and research
LINKS TO CITABLE LITERATURE help students expand their knowledge using primary sources of information